Er3+掺杂Li2O-SrO-ZnO-Bi2O3玻璃中Er3+离子在1.53 μm处的荧光发射特性

采用传统的熔融法制备了Er~(3+)掺杂的新型铋酸盐玻璃(Li_2O-SrO-ZnO-Bi_2O_3,LSZB),并对其光谱性质进行了表征,分析了玻璃的拉曼光谱、吸收光谱、荧光光谱,利用Judd-Ofelt理论研究了其荧光特性。LSZB玻璃样品中Er~(3+)的~4I_(13/2)→~4I_(15/2)跃迁发射峰位于1.53 μm处,半高宽约为78 nm。样品中Er~(3+)的~4I_(13/2)能级寿命为2.848 ms,量子效率为99.93%,受激发射截面达到9.76×10~(-21)cm~2。以上结果显示,Er~(3+)掺杂LSZB玻璃有良好的光谱特性。     

容器壁厚度对光栅衍射法测量液体折射率的影响

利用光栅衍射法测量了NaCl溶液的折射率,并分析了容器壁厚度引起的附加光程对折射率的影响.采用折射率修正公式运用一级衍射得到的溶液的折射率更可靠.     

A NEW METHOD FOR CALCULATING THE FUNDAMENTAL POTENTIAL FUNCTIONS INDUCED BY A SOURCE/DIPOLE POLYGON

In dealing with calculation of the normal potential velocity induced by a sourcepolygon there was a known result derived by Hess and Smith in terms of localcoordinates of the polygon’s corners and the point to be considered under acoordinate axis system located in the polygon.The present method in terms oftheir global coordinates is an alternative and extension to it.Hence,there is noneed to transform coordinates of points and integrate(?),etc.numerically in the calculation.     

Synthesis and electrochemical properties of copper(II), manganese(III) phthalocyanines bearing chalcone groups at peripheral or nonperipheral positions

In this study, new chalcone compound 1 , new phthalonitrile derivatives 2 and 3, new copper(II), manganese(III) phthalocyanines bearing chalcone groups at peripheral or nonperipheral positions were synthesized. Electrochemistry of tetra-(4-{(2 E )-3-[2-fluoro-4-(trifluoromethyl)phenyl]prop-2-enoyl}phenoxy) substituted Co(II)Pc and Mn(III)Pcs were studied with cyclic voltammetry (CV) to determine the redox properties of the phthalocyanines. According to the results, while the CuPcs 2a and 3a showed two Pc based reduction reactions and one Pc based oxidation reaction, MnPcs 2b and 3b gave two metal-based reduction reactions. All the redox processes are shifted toward positive potentials as a result of the increased electron-withdrawing ability of the trifluoromethyl substituents.     

盐酸副玫瑰苯胺褪色光度法测定铬(Ⅵ)

研究了显色剂盐酸副玫瑰苯胺与Cr2O72 -的褪色反应.发现在H2SO4介质中盐酸副玫瑰苯胺与Cr(Ⅵ)反应具有高灵敏的褪色现象.据此建立了测定Cr(Ⅵ)的光度法.当Cr(Ⅵ)质量浓度为0.01～2.0 mg/L时,盐酸副玫瑰苯胺的吸光度与Cr(Ⅵ)浓度符合朗伯-比耳定律,摩尔吸光系数为5.9×105 L·mol-1·...     

不同对流马赫数下光束畸变的实验研究

利用双曝光CCD相机成像技术,研究了小直径光束穿越可压缩混合层流场后所引起的气动光学效应.实验研究结果表明:在不同对流马赫数(Mc=0.17,0.45)下,光束投影(点扩散函数,PSF)发生了不同程度的变形和偏移.此外在不同对流马赫数下细光束投影都存在扩束、缩束和面积几乎不变的现象,但光束投影出现扩、缩束的概率不同.     

400W行波热声发电系统的实验研究

本文阐述了为太阳能发电系统设计的400 W行波热声发电系统(TWTAEG)的实验研究过程.实验系统由行波热声发动机和直线发电机组成,系统采用平均压力为3.5 MPa的氦-氩混合气体为工质,其中氩气分压比为1.4%,系统运行频率为74Hz.实验中最大输出电功为446 W,此时的热电效率为13%;在输出电功为416 W时热...     

基于β-环糊精对荧光桃红的荧光增敏作用的开关型荧光探针测定痕量镍

在pH 7.6的PBS介质中,且在PVA存在下,荧光桃红在其荧光发射峰555nm处的荧光强度因β-环糊精的加入而增强(荧光开),当在此体系中加入镍(Ⅱ)离子,其荧光发生猝灭(荧光关),其猝灭程度(ΔIf)与镍(Ⅱ)的质量浓度在5~300μg·L-1范围内呈线性关系,检出限(3S/N)为1.75μg·L-1。应用此"开关"型荧光探针测定了污水和矿石样品中镍的含量,并用标准加入法进行回收试验,测得回收率在98.8%~106%之间,测定值的相对标准偏差(n=10)在1.2%~2.2%之间。对此荧光体系的反应机理也作了初步探讨。     

流动性约束对我国城镇居民消费影响的实证分析

根据1978~2007年我国城镇居民消费和收入的相关数据,对我国城镇居民消费和流动性约束之间的关系进行了实证分析,并检验了流动性约束对消费的影响中是否包含了不确定性因素.分析结果表明:我国城镇居民消费受到较强的流动性约束制约;而流动性约束的测度受不确定性影响较小.     

特征幂零n-Lie代数

研究了一类特殊的幂零n-Lie代数,其所有导子都是幂零的,称其为特征幂零n-Lie代数.本文主要是得到了一般的n-Lie代数是特征幂零n-Lie代数的一些充要条件.